Developing O-Sialons
Sialons – based on the elements silicon (Si), aluminium (Al), oxygen (O) and nitrogen (N) – are a relatively new family of advanced ceramic materials. Some have high thermal resistance, some have extreme hardness and others have extreme toughness.The presence of nitrogen in the chemical structure of the ceramic is what makes the difference in terms of the properties the sialons show.
What is sialon?
Sialon is an acronym for silicon, aluminium, oxygen and nitrogen. In this video, IRL’s Dr Ian Brown explains how this new family of advanced ceramics are made and discusses some of their physical properties. He then goes on to explain how subtle changes in the formulation can allow sialons to be made with properties that fit a particular product or market.
Point of interest
What types of properties would a sialon need that is made to service the body armour market?
Acknowledgements:
Adrian Hape
Bill F18E777
CeCILL
Derek
John Murphy
Isbi Armor
Pyrotek
Materials scientists working at Industrial Research Limited (IRL) in Wellington, under the guidance of Dr Ian Brown, have developed an oxygen-enriched sialon called O-Sialon.
Its discovery came about as the result of what Ian describes as a “controlled accident”.
In order to improve the plasticity of an experimental sialon mix, Ian added some clay powder.
On analysing the sialon produced, it was found to have a little more oxygen present and a little less nitrogen.
Dr Ian Brown
Dr Ian Brown placing O-Sialon samples in the isostatic press. Before high temperature firing, the O-Sialon sample is compacted using an isostatic press. This ensures that the sample particles are tightly packed together prior to sintering.
This ‘new’ formulation was named O-Sialon, and it displayed excellent thermal shock resistance as well as being resistant to high temperature oxidation.
Nature of science
Sometimes discoveries in science are a result of unplanned and unforeseen laboratory procedures and processes. In the development of O-Sialon, Dr Ian Brown just happened to include clay into the mix of starting materials. It proved to be the ‘missing’ ingredient needed to turn failure into success.
The process of carefully blending clay, silica sand and silicon metal and heating to 1,500°C in an atmosphere of nitrogen has been patented in conjunction with an industrial partner.
O-Sialon is hard and tough with excellent thermal shock resistance. It can withstand rapid heating to high temperatures followed by rapid cooling over many cycles with little structural damage.
These properties have led to its use in the construction of pipes, tubes and conduits to contain and channel non-ferrous molten metals like aluminium and its alloys.
Body armour
One of the current research projects being conducted by Ian’s team at IRL is focused on developing lightweight O-Sialon body armour. The hardness, toughness, relative low density and virtual indestructibility of this advanced ceramic make it a prime candidate for such an application.
O-Sialon research at IRL
In this video, Dr Ian Brown explains how his materials research team at IRL developed an oxygen-rich sialon called O-Sialon. The excellent thermal shock resistance properties allied to high oxidation resistance have resulted in this advanced ceramic being used to fabricate refractories for use in the aluminium industry.
Points of interest
What is the melting point of aluminium?
How is aluminium produced?
Acknowledgement:
Pyrotek
The specific goal of the advanced ceramics programme developed by Ian is “to develop advanced ceramic materials and technologies related to their production and fabrication, to meet New Zealand’s current and future needs for these materials”.
O-Sialon production
This interactive shows the process of creating an advanced ceramic, O-Sialon, in the laboratory.
